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Sponges made from wood waste may soak up oil spills

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May 6, 2014

One of the modified nanocellulose sponges soaks up oil (red) while repelling water (blue)

One of the modified nanocellulose sponges soaks up oil (red) while repelling water (blue)

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As the Deepwater Horizon incident showed us, oil spills can be huge environmental disasters. That said, there are also considerable challenges in dealing with the waste products generated by the forestry and agriculture industries. Now, scientists from Switzerland's Empa research group have come up with a method of addressing the one problem with the other – they've developed sponges made from cellulose waste, that can soak up 50 times their own weight in oil.

The sponges are made from a chemically-modified version of what's called nanofibrillated cellulose (NFC), also known as nanocellulose.

Regular NFC is made by adding water to cellulose-containing materials (such as wood waste, discarded paper or agricultural by-products), extruding the resulting pulp at high pressure to create a gel, then freeze-drying the gel to remove the water. This results in a sponge made up of "long and interconnected cellulose nanofibres," that soaks up both oil and water.

For the sponges to be effective at cleaning up oil spills, however, it wouldn't do if they filled up with water before they could soak up much oil. Therefore, the Empa team mixes a reactive alkoxysilane molecule into the gel, before the freeze-drying process. This causes the sponge to lose its hydrophilic (water-absorbing) qualities, so it only sucks up oily liquids.

In lab tests, the sponges effectively removed substances such as engine oil, silicone oil, ethanol, acetone and chloroform from water samples, within a matter of seconds. Additionally, the oil-saturated sponges remain floating for easy retrieval, and they're biodegradable.

Empa is now working on scaling up the technology for use on a much larger (oil spill-sized) scale, and is seeking partners for its commercial development.

A paper on the research was recently published in the journal Chemistry of Materials.

Source: Empa

About the Author
Ben Coxworth An experienced freelance writer, videographer and television producer, Ben's interest in all forms of innovation is particularly fanatical when it comes to human-powered transportation, film-making gear, environmentally-friendly technologies and anything that's designed to go underwater. He lives in Edmonton, Alberta, where he spends a lot of time going over the handlebars of his mountain bike, hanging out in off-leash parks, and wishing the Pacific Ocean wasn't so far away.   All articles by Ben Coxworth
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4 Comments

Useful but bags of human hair does the same thing and would presumably be cheaper.

Slowburn
6th May, 2014 @ 07:21 pm PDT

Why can't they create some kind of suction device on an oil tanker and suck up oil spills?

ddl1061
7th May, 2014 @ 08:43 am PDT

If this can soak up oil but not water, it might be useful for extracting biofuels from water. That is, if oil fuels are created by algae in water, maybe this could extract it economically, assuming that you can squeeze out the oil after this sponge absorbs it.

Leithauser
7th May, 2014 @ 09:22 am PDT

@ ddl1061

They did. And in an assault on sanity and reason the 0bama administration prevented it from being used at the BP Deepwater Horizon spill because the discharged water from the centrifugal separator still contained slightly more oil than allowed bilge water discharge.

Slowburn
7th May, 2014 @ 03:38 pm PDT
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